Ideal and Non-ideal Solutions

IMPORTANT

Ideal and Non-ideal Solutions: Overview

This Topic covers sub-topics such as Azeotropic Mixtures, Ideal Solution, Ideal and Non-ideal solutions, Non-Ideal Solutions, Fractional Distillation of Ideal Solution, Fractional Distillation of Non-Ideal Solutions and, Maximum Boiling Point Azeotropes

Important Questions on Ideal and Non-ideal Solutions

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On mixing 25 ml of CCl4 with 25ml of toulene, the total volume of the solution is

EASY
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Which of the following are correct for an ideal solution?

a) ΔVmix=0

b) Vsolvent+Vsolute =Vsolution 

c) ΔHmix=0

d) H2O+CO2H2CO3 is an example of ideal solution.

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Which of the following is/are "not correct" for CH3OH+CH3COOH mixture solution?

a) ΔHmix<0

b) Does not obey Raoult's law

c) ΔHmix>0

d) An example of ideal solution

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IMPORTANT

The number of binary liquids which form ideal solutions among the following are

(1)Solution of benzene & toluene
(2) Solution of hexane & heptane
(3) Solution of chloroform & methanol
(4) Solution of methanol & acetone
(5) Solution of chloroform & acetone
(6) Solution of nitric acid & water
(7) Solution of Aniline & phenol

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Which of the mixture of solutions is an example for -Ve deviation from Raoult's law?

MEDIUM
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Identify the correct statement from the following

HARD
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Identify the correct statement from the following:

HARD
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Which represents correct difference when non-volatile solute is present in an ideal solution?

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What is azeotropic mixture? Can azeotropic mixture be considered as an ideal solution?

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Why does a solution of ethanol and cyclohexane show positive deviation from Raoult's lafw?

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Two liquids A and B on mixing produce a warm solution. Which type of deviation from Raoult's law does it show?

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Define an azeotropic mixture.

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Define an ideal solution.

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Under what conditions do non-ideal solutions show negative deviations?

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What is the boiling point of an azeotrope of non-ideal solution showing positive deviation as compared to the boiling of its components?

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What type of liquids form ideal solutions?

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Why pure ethyl alcohol cannot be obtained from rectified spirit 95.4% alcohol even by fractional distillation?

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The formation of a solution from two components can be considered as

(i) Pure solvent Separated solvent molecules, H1

(ii) Pure solute  Separated solute molecules, H2

(iii) Separated solvent and solute molecules  Solution, H3

Solution so formed will be ideal if

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Give reason, mixture of ethanol and acetone shows positive deviation from Raoult's law.

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Why a mixture of carbon disulphuide and acetone shows positive deviation from Raoult's law ? What type of azeotrope is formed by this mixture ?